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Cu(II)-Promoted Palladium-Catalyzed C–H Ortho-Arylation of N , N -Dimethylbenzylamines

✍ Scribed by Feng, Ruokun; Yao, Jinzhong; Liang, Zunjun; Liu, Zhanxiang; Zhang, Yuhong

Book ID
120042808
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
561 KB
Volume
78
Category
Article
ISSN
0022-3263

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## Abstract New, sterically demanding 1,3‐dialkylbenzimidazolium salts (**2a–c**) as __N__‐heterocyclic‐carbene precursors have been synthesized and characterized. The ortho position of aromatic aldehydes was directly and selectively arylated with aryl chlorides in the presence of a catalytic syste