CuII and PdII complexes of 3-hydroxy-1,3-bis(2-thienyl)prop-2-en-1-one
β Scribed by Baxter, L. A. M. ;Blake, A. J. ;Gould, R. O. ;Heath, G. A. ;Stephenson, T. A.
- Book ID
- 114509978
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 532 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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π SIMILAR VOLUMES
The geometric parameters of the title compound, C~13~H~7~Cl~3~OS, are in the usual ranges. The molecule is almost planar (r.m.s. deviation of all non-H atoms 0.193β Γ ). The dihedral angle between the two aromatic rings is 14.41β (7)Β°. The C=C double bond is __trans__ configured. The bond between the c
The enone fragment, the thiophene ring and the benzene ring of the title molecule, C 13 H 9 ClOS, are all essentially individually planar. The thiophene ring is disordered over two sites, corresponding to a rotation of approximately 180 about the single C-C bond to which it is attached. The crystal