The complete 1H and 13C assignment of two closely related isomeric triterpenoid derivatives (methyl 2a,3b-di-Oacetylolean-12-en-28-oate and methyl 2a,3a-di-O-acetylurs-12-en-28-oate) is described. In addition to 1D NMR methods, 2D shift-correlated NMR techniques (COSY, NOESY, HMBC and HMQC) were use
Cucurbitacins from Cayaponia racemosa: isolation and total assignment of 1H and 13C NMR spectra
✍ Scribed by Davina C. Chaves; João Carlos C. Assunção; Raimundo Braz-Filho; Telma L. G. Lemos; Francisco J. Q. Monte
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 108 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.1970
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✦ Synopsis
Abstract
Two new cucurbitane‐type triterpenoids, 2β,3β,16α,20(R),25‐pentahydroxy‐9‐methyl‐19‐norlanost‐5‐en‐7,22‐dione and 2β,3β,16α,20(R),25‐pentahydroxy‐9‐methyl‐19‐norlanost‐5‐en‐7,11,22‐trione, were isolated from fruits of Cayaponia racemosa. The total ^1^H and ^13^C chemical shift assignment of these two closely related compounds is described, making use of one‐ and two‐dimensional NMR techniques. Copyright © 2007 John Wiley & Sons, Ltd.
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