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[Cu4(ddtp)2Br4], a Unique Tetranuclear Copper(I) Complex with Bridging Thioethers and Bridging Bromides

✍ Scribed by Adrianus L. E. Stoffels; Willem G. Haanstra; Willem L. Driessen; Dr. Jan Reedijk

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
273 KB
Volume
29
Category
Article
ISSN
0044-8249

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An Experimental and Theoretical (DFT) Investigation of the Coordination Mode of 2,4-Dithiouracil (2,4-dtucH2) in Copper(I) Complexes with1,2-Bis(diphenylphosphanyl)benzene (dppbz): The Crystal Structures of [Cu(μ-Br)(dppbz)]2 and [CuBr(dppbz)(2,4-dtucH2)]
✍ Paraskevas Aslanidis; Philip J. Cox; Andreas Kaltzoglou; Athanasios C. Tsipis 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB

## Abstract Novel copper(I) mixed‐ligand complexes containing 1,2‐bis(diphenylphosphanyl)benzene (dppbz) and 2,4‐dithiouracil (2,4‐dtucH~2~) ligands have been synthesised by addition of the thione ligand to the dinuclear [Cu(μ‐X)(dppbz)]~2~ intermediate in acetonitrile/methanol or acetone solution.