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Cu2O and CuCl2·3Cu(OH)2corrosion products on copper rich dental amalgams
✍ Scribed by Marshall, Sally J. ;Lin, Jiin-Huey C. ;Marshall, Grayson W.
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 314 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0021-9304
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✦ Synopsis
Abstract
In addition to Sn‐rich corrosion products found in conventional amalgams, Cu‐rich amalgams also form Cu‐containing corrosion products. The nature of these Cu‐rich products was investigated by immersion of samples of 13 Cu‐rich amalgam systems in Ringer's solution for prolonged periods. SEM/EDS and x‐ray diffraction studies were used to identify the compounds formed and their morphology. Two products were identified: Cu~2~O, a red product, and CuCl~2~·3Cu(OH)~2~, a green product.
📜 SIMILAR VOLUMES
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê