{[Cu2Mo(C4N2S2)3(C2H3N)(C25H22P2)2]·2C4H10O·C2H3N}n

✍ Scribed by Fu, Wei-Wei ;Chen, Zhong-Ning

• Publisher: International Union of Crystallography
• Year: 2007
• Tongue: English
• Weight: 307 KB
• Volume: 63
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536807004679

✦ Synopsis

The reaction between Cu~2~(μ-dppm)~2~(MeCN)~2~~2~ and (Bu~4~N)~2~[Mo(mnt)~3~], where dppm is bis(diphenylphosphino)methane and mnt is cis-1,2-dicyanoethylene-1,2-dithiolate, gave the title compound, catena-Poly[[[acetonitrilebis[μ-bis(diphenylphosphino)methane-κ^2^
P:P′]dicopper(I)]-μ-(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)molybdenum(IV)]-μ-(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]. The binding between a Cu atom of the binuclear copper unit [Cu~2~(μ-dppm)~2~(MeCN)]^2+^ and two N atoms of the building block [Mo(mnt)~3~]^2−^ results in the formation of a one-dimensional zigzag chain structure.