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Cu-Catalyzed Couplings of Aryl Iodonium Salts with Sodium Trifluoromethanesulfinate

โœ Scribed by Cullen, Steven C.; Shekhar, Shashank; Nere, Nandkishor K.


Book ID
121363810
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
598 KB
Volume
78
Category
Article
ISSN
0022-3263

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Arylation and alhenylation of 1-ethoxy-l-trimetylsilyloxycyclopropane with diphenyliodonium tetrafluoroborate and alkenyliodonium tetrafluoroborate were accomplished by slow addition of silyloxycyciopropane to iodonium salts in the presence of Pd( OAc) 2 (2 tool %) and DME/H20 (4 : 1) to afford ~ su