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Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes

✍ Scribed by Liu, Ping; Fukui, Yuki; Tian, Ping; He, Zhi-Tao; Sun, Cai-Yun; Wu, Nuo-Yi; Lin, Guo-Qiang

Book ID
120618712
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
831 KB
Volume
135
Category
Article
ISSN
0002-7863

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Chiral C 2 -symmetric N-heterocyclic carbenes (NHCs) were tested for their stereocontrolling abilities in gold(I)-catalyzed asymmetric cyclization of 1,6-enynes giving the corresponding cyclopentane derivatives with moderate enantioselectivity of up to 59%.