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Cs8.5W15O48 and CSW2O6: Members of a New Homologous Series of Cesium Tungsten Oxides

✍ Scribed by R.J. Cava; R.S. Roth; T. Siegrist; B. Hessen; J.J. Krajewski; W.F. Peck Jr.

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
260 KB
Volume
103
Category
Article
ISSN
0022-4596

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✦ Synopsis

The crystal structures of two new reduced cesium tungsten oxides are reported. Along with the previously reported compound (\mathrm{Cs}{6} \mathrm{~W}{11} \mathrm{O}{36}), they represent several members of a homologous series of layer compounds between the hexagonal tungsten bronze and pyrochlore structure types. The series formula is [A] (\mathrm{Cs}{2 n} \mathrm{~W}{4 n-1} \mathrm{O}{12 n}), where (n-1) is the number of pyrochlore layers. 1993 Academic Press. Inc.

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