Crystallographic, X-ray Absorption, and IR Studies of Solid- and Solution-State Structures of Tris(nitrato) N,N , N ‘, N ‘-Tetraethylmalonamide Complexes of Lanthanides. Comparison with the Americium Complex
✍ Scribed by Den Auwer, C.; Charbonnel, M. C.; Drew, M. G. B.; Grigoriev, M.; Hudson, M. J.; Iveson, P. B.; Madic, C.; Nierlich, M.; Presson, M. T.; Revel, R.; Russell, M. L.; Thuéry, P.
- Book ID
- 121406583
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 128 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Lanthanide complexes of a hexaaza macrocyclic ligand containing a pyridine head unit (L) were synthesized (Ln = La–Lu, except Pm). The solid‐state structures of the corresponding La, Ce, Pr, Nd, and Lu complexes were determined by single‐crystal X‐ray crystallography, and they reveal th
The results obtained are given in Table II. From the AH" and AS' values it can be seen that the observed stability is entropic in origin. 1