Crystallographic study on metal sulphide-active material for cadmium ion-selective electrodes

✍ Scribed by F. Pál; K. Tóth; E. Pungor; M. Farkas-Jahnke; H. Ebel; M.F. Ebel

• Publisher: Elsevier Science
• Year: 1986
• Tongue: English
• Weight: 650 KB
• Volume: 180
• Category: Article
• ISSN: 0003-2670
• DOI: 10.1016/0003-2670(86)80013-7

✦ Synopsis

Correlation between the electrochemical function of ion-selective electrodes made of differently prepared mixed sulphides and their crystalline structure was investigated . X-ray diffraction and x-ray photoelectron spectroscopy reveal recrystallization of CdS on Ag,S grains during co-precipitation or co-milling . This study supports the idea that there is a strong correlation between the electrochemical function and crystalline properties of the electrode materials .