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Crystallographic studies on cation substitutions in the system (Na,K) (V,P)O3

✍ Scribed by K.L. Idler; C. Calvo; H.N. Ng


Book ID
107817931
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
670 KB
Volume
25
Category
Article
ISSN
0022-4596

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Na3V4+O(PO4)(HPO4), a New Phase in the N
✍ Michael Schindler; Werner Joswig; Werner H. Baur πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 218 KB

A new examination of the Na/V/P/H 2 O systems at 473 K under hydrothermal conditions yielded in a pH range between 6.5 and 7.6 and at synthesis times longer than 10 days a new blue Na 3 VO(PO 4 )(HPO 4 ) phase. It crystallizes in space group P2 1 /m with a ‫؍‬ 9.6402(7) A s , b ‫؍‬ 6.4075(5) A s , c