Crystallographic Studies of Synthetic Corrinoids. III. Structural similarities and differences between A/D-seco-corrinoid complexes of divalent nickel, palladium and platinum

Crystallographic Studies of Synthetic Co

Crystallographic Studies of Synthetic Corrinoids. II. Molecular structure of a C/D-seco-corrinoid nickel(II) complex

✍ M. Dobler; J. D. Dunitz 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 German ⚖ 456 KB

D , = 1.39; space group Pi-(assumed from racemic nature of synthetic product). c) Crystallized from methanolethyl acetate solution: monoclinic, a = 9.94, b = 21.12, c = 14.9 A, = 92"55', V = 3039 A3, D , = 1.32 (assuming 2 = 4), D , = 1.35; space group PZJn (2nd setting). d ) Crystallized from metha