Crystallographic report: tert-Butyldifluoro(2,4,6-tris-iso-propylphenyl)silane, t-Bu(2,4,6-i-PrC6H2)SiF2
β Scribed by Rudolf Pietschnig; Ferdinand Belaj
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 100 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.621
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β¦ Synopsis
Abstract
Owing to steric congestion within the title compound, the geometry at the silicon atom deviates slightly from ideal tetrahedral geometry with an increased Cο£ΏSiο£ΏC angle of 115.97(12)Β° and an elongated Siο£ΏC~aryl~ bond distance. Copyright Β© 2004 John Wiley & Sons, Ltd.
π SIMILAR VOLUMES
Inhaltsu Γ bersicht. Bei der Umsetzung von [(Mo 6 I i 8 )I a 6 ] 2Β± mit (SCN) 2 in Dichlormethan bei Β±20 Β°C entsteht das Hexaisothiocyanato-Clusteranion [(Mo 6 I i 8 )(NCS) a 6 ] 2Β± . Die Ro Γ ntgenstrukturanalyse an einem Einkristall von (n-Bu 4 N) 2 [(Mo 6 I i 8 )(NCS) a 6 ] Β΄2 Me 2 CO (monoklin,