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Crystallographic report: tert-Butyldifluoro(2,4,6-tris-iso-propylphenyl)silane, t-Bu(2,4,6-i-PrC6H2)SiF2

✍ Scribed by Rudolf Pietschnig; Ferdinand Belaj


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
100 KB
Volume
18
Category
Article
ISSN
0268-2605

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✦ Synopsis


Abstract

Owing to steric congestion within the title compound, the geometry at the silicon atom deviates slightly from ideal tetrahedral geometry with an increased Cο£ΏSiο£ΏC angle of 115.97(12)Β° and an elongated Siο£ΏC~aryl~ bond distance. Copyright Β© 2004 John Wiley & Sons, Ltd.


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Inhaltsu È bersicht. Bei der Umsetzung von [(Mo 6 I i 8 )I a 6 ] 2± mit (SCN) 2 in Dichlormethan bei ±20 °C entsteht das Hexaisothiocyanato-Clusteranion [(Mo 6 I i 8 )(NCS) a 6 ] 2± . Die Ro È ntgenstrukturanalyse an einem Einkristall von (n-Bu 4 N) 2 [(Mo 6 I i 8 )(NCS) a 6 ] ´2 Me 2 CO (monoklin,