## Abstract The crystal structure of [(__p__โCH~3~C~6~H~4~)~3~GeCH(__o__โCH~3~C~6~H~4~)CH~2~CO~2~]~2~Sn(C~4~H~9~)~2~ consists of a monomer with the atoms of tin and germanium both occupying tetrahedral geometries. However, the tin atom is distorted towards a skew trapezoidal bipyramid geometry as a
Crystallographic report: Polymeric [3-(triphenylgermyl)-3-o-methoxyphenylpropionato]trimethyltin(IV)
โ Scribed by Muhammad Kaleem Khosa; Masood Parvez; Muhammad Mazhar; Saqib Ali
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 71 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.748
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โฆ Synopsis
The polymeric chains of [Sn(CH 3 ) 3 (C 28 H 25 O 3 Ge)] n contain trimethyltin moieties bridging two neighboring 3-(triphenylgermyl)-3-o-methoxypropionate ligands via carboxyl groups. The germanium atom has a distorted tetrahedral geometry and the tin atom has a distorted trigonalbipyramidal geometry, the latter with three methyl groups in the equatorial plane and oxygen atoms defining the axial positions.
๐ SIMILAR VOLUMES
## Abstract A twoโdimensional layer structure is found in the title compound comprising interconnected 22โmembered rings and __trans__โC~3~O~2~ trigonal bipyramidal coordination geometries for tin. Copyright ยฉ 2003 John Wiley & Sons, Ltd.