The centrosymmetric title compound, [Cd 2 {CH 3 OC 6 H 4 P(OC 5 H 9 )S 2 } 4 ], features an eight-membered [-Cd-S-P-S-] 2 ring owing to the presence of bridging dithiolate ligands. Tetrahedral coordination geometries for cadmium are completed by chelating ligands.
✦ LIBER ✦
Crystallographic report: Bis{µ-[O-cyclopentyl(4-methoxyphenyl) dithiophosphonato]1κ:S,2κ:S-[O-cyclopentyl(4-methoxyphenyl)dithiophosphonato]1κ2S,S′} dizinc(II)
✍ Scribed by Mehmet Karakus; Hamza Yilmaz; Ece Bulak; Peter Lönnecke
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 79 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.850
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## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_