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Crystallographic Data 160. Molybdenum Metaphosphate, Mo(PO3)3

โœ Scribed by Douglass, R; Staritzky, Eugene


Book ID
115311432
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
97 KB
Volume
29
Category
Article
ISSN
0003-2700

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Structure of the Trivalent Molybdenum Me
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Crystals of the molybdenum(III) metaphosphate \(\mathrm{Mo}\left(\mathrm{PO}_{3}\right)_{3}\) were grown by chemical vapor transport with iodine ( \(1173 \mathrm{~K} \rightarrow 1073 \mathrm{~K})\). The structure was determined by single crystal \(\mathrm{X}\)-ray diffraction. \(\mathrm{Mo}\left(\ma

A Mixed Valent Molybdenum Monophosphate
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A new mixed-valent molybdenum monophosphate Li 3 Mo 3 O 5 (PO 4 ) 3 with an original structure has been isolated. It crystallizes in the space group P1 with a โ€ซุโ€ฌ 11.964, b โ€ซุโ€ฌ 12.716, c โ€ซุโ€ฌ 8.274 A s , โ€ซุโ€ฌ 90.26ยฐ, โ€ซุโ€ฌ 96.87ยฐ, and โ€ซุโ€ฌ 89.67ยฐ. It is to date the only mixed-valent molybdenum phosphate

A Monophosphate Molybdenum Bronze Built
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A monophosphate molybdenum bronze Ag 2.8 (PO 2 ) 4 (MoO 3 ) 12 has been synthesized for the first time. This monoclinic bronze (a โ€ซุโ€ฌ 23.857(3) A s s , b โ€ซุโ€ฌ 5.2990(6) A s s , c โ€ซุโ€ฌ 6.5659(4) A s s , โ€ซุโ€ฌ 93.950(6)ยฐยฐ), represents the m โ€ซุโ€ฌ 6 member of the A x (PO 2 ) 4 (MO 3 ) 2m family (M โ€ซุโ€ฌ W, Mo)