Crystallographic Characterization of a Palladium(II) Metallamacrocycle Supported by an Amino-Functionalized Ferrocene and Its Use as an Efficient Suzuki-Coupling Catalyst

Benzene benzimidazole containing Pd(II)

Benzene benzimidazole containing Pd(II) metallacycle: Synthesis, X-ray crystallographic characterization and its use as an efficient Suzuki coupling catalyst

✍ Sachindranath Pal; Wen-Shu Hwang; Ivan J.B. Lin; Chen-Shiang Lee 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 573 KB

A first example of a highly stable benzimidazole N-donor dinuclear palladacycle complex is reported. X-ray diffraction analysis showed that two ligands assembled through complexation to two palladium(II) ions to give a compressed rectangular shaped metallamacrocycle. This complex catalyzed Suzuki co