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Crystallochemical causes of the different thermal properties of [Cu(py)2(NCS)2] and [Cu(4-Mepy)2(NCS)2] complexes

✍ Scribed by M. Kabešová; Z. Kozfšková; M. Dunaj-Jurco


Publisher
Springer Netherlands
Year
1992
Tongue
English
Weight
270 KB
Volume
38
Category
Article
ISSN
0022-5215

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A 2:2:1:6 molar ratio of Zn(ClO 4 ) 2 Á6H 2 O, tris(2-aminoethyl)amine (tren), Zn(ClO 4 ) 2 Á6H 2 O/Cu(ClO 4 ) 2 Á6H 2 O and NH 4 NCS in methanol-water solution mixtures affords homo-/heterobimetallic compounds of the type [Zn(tren)NCS] 2 [M(NCS) 4 ] (M = Zn, 1; M = Cu, 2) which have been characteri