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Crystallization: Kinetics and design considerations

✍ Scribed by D. C. Timm; T. R. Cooper


Publisher
American Institute of Chemical Engineers
Year
1971
Tongue
English
Weight
353 KB
Volume
17
Category
Article
ISSN
0001-1541

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✦ Synopsis


Abstract

The following nucleation rate and growth rate relationships for the aqueous, continuous, cooling crystallization of potassium dichromate were determined from experimental crystal size distributions: J = 3.9 Γ— 10^10^ (C – C~eq~)^0.9^; r = 3.0 Γ— 10^3^ (C – C~eq~)^1.7^. Since nucleation rate is of lower kinetic order than growth rate, higher levels of supersaturation will yield crystal distributions with a larger mean size. Therefore for this system, batch or plug‐flow reactors are preferred to continuous‐stirred tanks.


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