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Crystalline-state racemization of a chiral cyanoethyl group connected by a hydrogen bond

✍ Scribed by Takenaka, Y. ;Ohashi, Y. ;Tamura, T. ;Uchida, A. ;Sasada, Y. ;Ohgo, Y. ;Baba, S.


Book ID
114514889
Publisher
International Union of Crystallography
Year
1993
Tongue
English
Weight
624 KB
Volume
49
Category
Article
ISSN
0108-7681

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The first example of optically active compound 3c which possesses axial chirality based on the N(open-chain imide)-Ar bond rotation, is described. Furthermore, a quite interesting result is also described, namely, that 3a bearing a bulky acyl group rather than a small one racemized more rapidly. To