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Crystalline electric field in the Ce(Zn1−xCux)2 system

✍ Scribed by P. Morin; D. Gignoux; J. Voiron; A.P. Murani

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
233 KB
Volume
180-181
Category
Article
ISSN
0921-4526

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✦ Synopsis

The orthorhombic compounds Ce(Zn,_,Cu,), are good candidates to study the evolution of the magnetic properties toward the Kondo state. Magnetic susceptibility, measured along the three main axes on single crystals, and neutron spectroscopy have allowed us to study the evolution of the CEF in this system.

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Pseudo binary alloys like R(A1-xBx)2 compounds are known to exhibit both negative and positive types of deviation from Vegard's law on substitution of 3d or 4f cations. CeNi2 based alloys are known to be mixed valence compounds whereas CeFe2 alloys are probably not. In this study we examine the infl