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Crystal-to-Crystal Solid-State Photochemistry: Absolute Asymmetric β-Thiolactam Synthesis from an Achiral α,β-Unsaturated Thioamide

✍ Scribed by Sakamoto, Masami; Takahashi, Masaki; Kamiya, Kenji; Yamaguchi, Kentaro; Fujita, Tsutomu; Watanabe, Shoji


Book ID
125996038
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
158 KB
Volume
118
Category
Article
ISSN
0002-7863

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Solid-State Photochemistry: Absolute Asy
✍ Masami Sakamoto; Masaki Takahashi; Wataru Arai; Takashi Mino; Kentaro Yamaguchi; 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 213 KB

AbstractÐSeveral types of achiral N,N-dibenzyl-a,b-unsaturated thioamides were subjected to X-ray crystallographic analysis, and it was revealed that methylcrotonthioamide and 1-cyclohexenecarbothioamide provided chiral crystals. The absolute con®guration determined by anomalous scattering method co