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Crystal structures of three host–guest complexes of methylsubstituted cucurbit[6]urils and anthracene derivatives

✍ Scribed by Ze-Hua Chen; Fa-Geng Zhou; Yun-Qian Zhang; Qian-Jiang Zhu; Sai-Feng Xue; Zhu Tao

Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
672 KB
Volume
930
Category
Article
ISSN
0022-2860

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20 times more rapid is the complexation of the organic ammonium ion receptor cucurbit[6]uril (CB6) with cyclohexylmethylamine than with the cyclohexylmethylammonium species. Within the narrow pH region around the pK value of the amine, the complexation kinetics are accelerated but the binding consta