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Crystal structures of the compounds Ni3Te2, Ni3−δTe2 (δ=0.12) and Ni1.29Te

✍ Scribed by L.D Gulay; I.D Olekseyuk

Book ID
116597587
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
402 KB
Volume
376
Category
Article
ISSN
0925-8388

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The compounds [NEt,],[Ni$e,(Se,),(Se,)] axNEt& (x= 0, 1) and [NEt&[Ni.,Te4(Te2)2(Te3)41 have been prepared from the reaction in DMF of Ni(S2COEt)2 with L&Se and Se or Li,Te and Te, respectively. These compounds result from spontaneous assembly reactions in which Nix1 centers are oxidized to Niw with