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Crystal structures of the 1/1 adducts of diphenylcyclopropenone with 3-triphenylstannyloxy-4,5-dimethylisothiazole 1,1-dioxide and 3-triphenylstannyloxybenzisothiazole 1,1-dioxide

✍ Scribed by Weng Ng Seik; V.G.Kumar Das; Yip Wai-Hing; Thomas C.W. Mak


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
452 KB
Volume
456
Category
Article
ISSN
0022-328X

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cis-disulfoxide 4, or -1,1,5,5\_tetraoxide: disulfone 6 can be accomplished with potassium permanganate and a phase transfer catalyst in a two phase system in 66% yield, with sodium metaperiodate in aqueous methanol in 95% yield, or ruthenium tetraoxide in 70% yield, respectively. Oxidation of the k