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Crystal structures of some manganese(II) and cadmium hexacyanoferrates (II,III) and structural transformations related to the sorption of Cesium

✍ Scribed by Martínez-García, R.; Reguera, E.; Rodriguez, J.; Balmaseda, J.; Roque, J.

Book ID
120944793
Publisher
International Centre for Diffraction Data
Year
2004
Tongue
English
Weight
255 KB
Volume
19
Category
Article
ISSN
0885-7156

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Sorption Mechanisms of Cesium on CuII2Fe
Sorption Mechanisms of Cesium on CuII2FeII(CN)6and CuII3[FeIII(CN)6]2Hexacyanoferrates and Their Relation to the Crystalline Structure
✍ S Ayrault; B Jimenez; E Garnier; M Fedoroff; D.J Jones; C Loos-Neskovic 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 358 KB

Cu II 2 Fe II (CN) 6 • xH 2 O and Cu II 3 [Fe III (CN) 6 ] 2 • xH 2 O can be prepared with reproducible chemical compositions and structures after careful washing. They have cubic Fm3 m structures with iron vacancies. In Cu II 2 Fe II (CN) 6 , copper occupies two different sites: Cu1 in position 4b