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Crystal structures of bis(cyclopentadienyldicarbonyliron)sodium tetrahydrofuran and (cyclopentadienyldicarbonyliron)sodium tetramethylethylenediamine complexes

✍ Scribed by Ninghai Hu; Guojun Nie; Zhongsheng Jin; Wenqi Chen


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
455 KB
Volume
377
Category
Article
ISSN
0022-328X

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An improved synthesis of 3,5-bis(trifluoromethyl)pyrazole (1) is described. This compound was used for the high-yield syntheses of the tris(pyrazoly1)borates Nd [HB(3,,-pz),1 (2a) and the corresponding potassium salt, 2b, starting from 1 and NaBH, and KBH,, respectively. A convenient route to the co