Crystal structures of 2-(2-methoxyphenyl) perimidine and its hemihydrate
✍ Scribed by Concepción Foces-Foces; Antonio L. Llamas-Saiz; Rosa Mariá Claramunt; Dionisia Sanz; Julio Dotor; José Elguero
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 546 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1572-8854
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The title compound (C 15 H 12 N 3 OSCl) crystallizes in the monoclinic space group P2 1 /n with a = 11.211( 3), b = 8.106(2), c = 17.494(4) Å, β = 104.49(2)º, V = 1539.2(7) Å 3 , Z = 4, D cal = 1.371 Mg/m 3 at T = 293 K. The structure was solved by direct methods and refined by full-matrix least-squ
The crystal and molecular structures of tris(panisyl)tin acetate (1) (p-anisyl =p-methoxyphenyl) and trimesityltin acetate (2) (mesityl= 2,4,64rimethylphenyI) have been determined. Both have monomeric structures with the acetate group acting as an asymmetric bidentate ligand. Bond valence analysis o