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Crystal Structures and Spectra of Two Forms of Chloro(triphenylarsine)gold(I)

✍ Scribed by Weissbart, B.; Larson, L. J.; Olmstead, M. M.; Nash, C. P.; Tinti, D. S.

Book ID: 127281586
Publisher: American Chemical Society
Year: 1995
Tongue: English
Weight: 286 KB
Volume: 34
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00105a060

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## Abstract The reaction of copper(I) chloride with acetonethiosemicarbazone (tscac) in a copper to tscac molar ratio of 1:2 forms the cationic complex [Cu(tscac)~2~]Cl (1). When the ratio of the copper to tscac was reduced to 1:1, a dimeric complex [Cu~2~Cl~2~(tscac)~2~]~2~ (2) was obtained. In co