Crystal structures and properties of divalent transition metal decahydro-Closo-Decaborate hydrates [M(H2O)6][B 10H10] ̇ 2H2O (M = Mn, Fe, Co, Ni, Zn)
✍ Scribed by Zimmermann, Lucas W. (author);Schleid, Thomas (author)
- Book ID
- 121430728
- Publisher
- Oldenbourg Wissenschaftsverlag
- Year
- 2013
- Tongue
- English
- Weight
- 284 KB
- Volume
- 288
- Category
- Article
- ISSN
- 2194-4946
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## Abstract Crystals of Zn(NO~3~)~2~· H~2~O and Mn(NO~3~)~2~· 2 H~2~O were synthesized by heating melts of the respective penta- or hexahydrates. Single crystal X-ray diffraction of the two highly hygroscopic phases reveals new sheet-structure types: Zn(NO~3~)~2~· H~2~O [__Pbca__,__a__= 9.722(1),__
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