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Crystal Structures and Packing of the Tricarbonylbis(phosphine)iron(0) Complexes trans -Fe(CO) 3 L 2 (L = PPh 2 Me, PPh 3 ). Interplay between Arene−Arene Interactions and Phosphine Conformations

✍ Scribed by Glaser, Rainer; Haney, Paul E.; Barnes, Charles L.


Book ID
126153594
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
225 KB
Volume
35
Category
Article
ISSN
0020-1669

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## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo