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Crystal Structures and Ferromagnetic Properties of Two New Dinuclear Complexes with Thiocyanato Bridging Ligands:{[Ni2(1,2-diamino-2-methylpropane)3(NCS)2]2(.mu.-NCS)2}[Ni(1,2-diamino-2-methylpropane)2(NCS)2].cntdot.H2O and[{Ni2(1,2-diamino-2-methylpropane)4}(.mu.-NCS)2](PF6)2. Magneto-Structural Correlations

✍ Scribed by Monfort, Montserrat; Ribas, Joan; Solans, Xavier

Book ID: 127023278
Publisher: American Chemical Society
Year: 1994
Tongue: English
Weight: 688 KB
Volume: 33
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00097a013

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## Abstract Reaction of Ni(ClO~4~)~2~·6H~2~O with bis(3‐aminopropyl)amine (dpt) and ammonium thiocyanate produces the novel thiocyanato‐bridged nickel(II) compound [Ni(μ‐NCS)(dpt)(NCS)]~2~[Ni(μ‐NCS)(dpt)(NCS)]~4~, which has been structurally characterised. The structure determination reveals that t