Crystal Structures – A Manifesto for the Superiority of the Valine-Derived 5,5-Diphenyloxazolidinone as an Auxiliary in Enantioselective Organic Synthesis

Silver Compounds in Synthetic Chemistry.

Silver Compounds in Synthetic Chemistry. 1 A Facile Preparative Route for Pentafluorophenylsilver, AgC6F5 and its Use as an Oxidative Pentafluorophenyl Group Transfer Reagent in Reactions with Group 12 to 16 Elements — the Single Crystal Structure of AgC6F5 · EtCN, the First Arylsilver Derivative Crystallising in Infinite Chains

✍ Wieland Tyrra; Mathias S. Wickleder 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 173 KB 👁 2 views

AgC 6 F 5 is directly and quantitatively formed from room temperature reactions of AgF and Me 3 SiC 6 F 5 in N-donor solvents, particularly EtCN. Solutions of AgC 6 F 5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the c