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Crystal structure of the lead bromo-borate Pb2[B5O9]Br from precision single-crystal X-ray diffraction data and the problem of optical nonlinearity of hilgardites

✍ Scribed by E. L. Belokoneva; A. G. Al-Ama; S. Yu. Stefanovich; P. A. Plachinda


Book ID
111437832
Publisher
SP MAIK Nauka/Interperiodica
Year
2007
Tongue
English
Weight
283 KB
Volume
52
Category
Article
ISSN
1063-7745

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A; a ¼ 116:779ð2Þ; b ¼ 96:089ð3Þ; g ¼ 84:000ð3Þ1; R F ¼ 0:033: The disulphate anions are essentially eclipsed. All three structures can be described as dichromate-like, where the alkali cations coordinate oxygens of the isolated disulphate groups in three-dimensional networks. The K-O and Na-O coord