Femtosecond transient absorption studies of charge-transfer complexes of 12 with hexamethylbenzene have been performed in a series of noncomplexing solvents. Anisotropy measurements of the bleach of the charge-transfer absorption band indicate that the geometry and electronic structure of the comple
Crystal structure of the charge transfer complex 9-cyclohexyladenine-iodine
β Scribed by Dick van der Helm
- Publisher
- Springer
- Year
- 1973
- Tongue
- English
- Weight
- 489 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1572-8854
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π SIMILAR VOLUMES
Femtosecond spectroscopy is used to investigate the ultrafast photochemistry of the I,: arene charge-transfer complex that occurs upon excitation into the charge-transfer state. We find that the photo-excited complex branches into two different channels within 25 fs. The dominant channel involves br
Alutrnct--12 complexes with triptycene and several di-and triaryl derivatives of methane and ethane were studied. For these complexes the values of 2or are virtually identical to those reported for the complexes with the analogous monoaryl donors, while the values of,~ for their blue shifted 12 peak