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Crystal Structure of the All-Ferrous [4Fe-4S]0 Form of the Nitrogenase Iron Protein from Azotobacter vinelandii†,‡

✍ Scribed by Strop, Pavel; Takahara, Patricia M.; Chiu, Hsiu-Ju; Angove, Hayley C.; Burgess, Barbara K.; Rees, Douglas C.


Book ID
115317066
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
232 KB
Volume
40
Category
Article
ISSN
0006-2960

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Nitrogenase of Azotobacter vindandii is sensitive to oxygen, and sensitivity develops during purification. Such inactivation is well prevented by 0.1% hydroquinone plus 0.01 ~ ascorbate, which are also effective in preventing inactivation of enzyme on storage under H2. Activity is proportional to fe