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Crystal structure of tetraoxa[4]peristylane: Novel CH…O mediated architecture in the solid state

✍ Scribed by Goverdhan Mehta; Ramdas Vidya; Kailasam Venkatesan

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
238 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

In the crystal, the molecules of 'oxa-bowl' 3 are interconnected in rim-up, rim-down fashion through an extensive network of C(sp3)-H...O hydrogen bonds involving even a non acidic cyclobutane ring hydrogen, leading to a multi-columnar arrangement of bowls and a 3D interpenetrating C-H... O net.

📜 SIMILAR VOLUMES

A novel architecture in solid state with
A novel architecture in solid state with extensive network of CH…O interactions. X-ray crystal structure of the ‘oxa-bowl’ pentaoxa[5]peristylane
✍ Goverdhan Mehta; Ramdas Vidya 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 244 KB

In the crystal, the "oxa-bowl" 3 (C10H1005) possesses a fascinating columnar architecture built around numerous C-H...O interactions, in which all the ten CH units and five oxygen atoms (through both the lone pairs) are involved.

ChemInform Abstract: Oxa Bowls: Synthesi
ChemInform Abstract: Oxa Bowls: Synthesis and C—H×××O Mediated Solid State Structure of Pentaoxa-[5]-peristylane.
✍ Goverdhan Mehta; Ramdas Vidya 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB 👁 2 views

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