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Crystal Structure of SrAl2B2O7 and Eu2+ Luminescence

✍ Scribed by F. Lucas; S. Jaulmes; M. Quarton; T. Le Mercier; F. Guillen; C. Fouassier


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
274 KB
Volume
150
Category
Article
ISSN
0022-4596

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✦ Synopsis


The crystal structure of strontium dialuminodiborate SrAl 2 B 2 O 7 has been established by single-crystal X-ray di4raction methods. The compound crystallizes in the trigonal system (space group R3 c, Z ‫؍‬ 6) with cell parameters a ‫؍‬ 4.893(1) A > and c ‫؍‬ 47.78(1) A > . Aluminium and boron atoms are, respectively, in tetrahedral and triangular oxygen coordination. The assembly of Al 2 O 7 units and BO 3 triangles forms double layers between which Sr 2Ψ‰ ions are located. The Eu 2Ψ‰ -doped crystalline powder exhibits a luminescence band with maximum at 415 nm. Luminescence characteristics are compared to those of other strontium borates.


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