Crystal Structure of SrAl2B2O7 and Eu2+ Luminescence
β Scribed by F. Lucas; S. Jaulmes; M. Quarton; T. Le Mercier; F. Guillen; C. Fouassier
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 274 KB
- Volume
- 150
- Category
- Article
- ISSN
- 0022-4596
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β¦ Synopsis
The crystal structure of strontium dialuminodiborate SrAl 2 B 2 O 7 has been established by single-crystal X-ray di4raction methods. The compound crystallizes in the trigonal system (space group R3 c, Z β«Ψβ¬ 6) with cell parameters a β«Ψβ¬ 4.893(1) A > and c β«Ψβ¬ 47.78(1) A > . Aluminium and boron atoms are, respectively, in tetrahedral and triangular oxygen coordination. The assembly of Al 2 O 7 units and BO 3 triangles forms double layers between which Sr 2Ψ ions are located. The Eu 2Ψ -doped crystalline powder exhibits a luminescence band with maximum at 415 nm. Luminescence characteristics are compared to those of other strontium borates.
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