Synthetic La 2 Cu(SeO 3 ) 4 is built up from infinite anionic sheets of square-planar CuO 4 and pyramidal SeO 3 groups, connected ia Cu-O-Se bonds. Ten-coordinate La III species and a second selenite group complete the structure. La 2 Cu(SeO ) 4 is isostructural with Bi 2 Cu(SeO 3 ) 4 -II. Crystal d
Crystal structure of Li2Cu3(SeO3)2(SeO4)2
β Scribed by Gerald Giester
- Publisher
- Springer Vienna
- Year
- 1989
- Tongue
- English
- Weight
- 356 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0026-9247
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The decomposition of Er 2 (SeO 4 ) 3 in the presence of LiF in a sealed gold ampoule at 8701C yielded single crystals of Er 2 (SeO 3 ) 3 . The triclinic crystal structure (P 1 1; Z ΒΌ 2; a ΒΌ 698:2Γ°1Γ; b ΒΌ 800:6Γ°1Γ; c ΒΌ 895:0Γ°1Γ pm; a ΒΌ 71:38Γ°1Γ; b ΒΌ 70:13Γ°1Γ; c ΒΌ 65:87Γ°1Γ1; R all ΒΌ 0:0364) contains t