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Crystal structure of cyclo(Gly-L-Pro-D-Phe-Gly-Val): an example of a new type of three-residue turn

โœ Scribed by Stroup, A. N.; Rheingold, A. L.; Rockwell, A. L.; Gierasch, L. M.


Book ID
126897540
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
572 KB
Volume
109
Category
Article
ISSN
0002-7863

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Accommodation of a D-Phe residue into a
โœ I. L. Karle; J. L Flippen-Anderson; K. Uma; P. Balaram ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 535 KB

OMe (I), which is an analogue of the N-terminal sequence of antiamoebins and emerimicins, establishes a completely 3,0-helical conformation with seven successive intramolecular 4 + 1 hydrogen bonds. The average, 4,+ values for residues 1-8 are -59" and -32", respectively. Crystal parameters are C47H