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Crystal structure of bis(triphenylphosphine)chloro-1,3-di-p-tolyltriazenidopalladium(II)

✍ Scribed by Bombieri, G.; Immirzi, A.; Toniolo, L.

Book ID
126246280
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
723 KB
Volume
15
Category
Article
ISSN
0020-1669

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Di-μ-phenyl­selenolato-bis­[chloro(tri­p
Di-μ-phenyl­selenolato-bis­[chloro(tri­phenyl­phosphine)­palladium(II)]
✍ Hannu-Kuure, Milja S. ;Oilunkaniemi, Raija ;Laitinen, Risto S. ;Ahlgren, Markku 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 312 KB

The title compound, [Pd 2 Cl 2 ("-C 6 H 5 Se) 2 (C 18 H 15 P) 2 ], crystallizes as a centrosymmetric phenylselenolato-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with the PdÐSe distance trans to the terminal Cl À ligand at 2.4174 (