Crystal Structure of Bis[acetone-1-naphthoylhydrazinato(−1)]copper(II) and Investigations of Intermolecular Interactions
✍ Scribed by Zoran D. Tomić; Vukadin M. Leovac; Srdjan V. Pokorni; Dieter Zobel; Snežana D. Zarić
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 109 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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Copper(II) complexes containing b-diketonato ligands of the general formula [Cu{(4-RO)C 6 H 4 COCH-COC 6 H 4 (4-OR)} 2 ] 3 (R Bu) or 4 (R Ph) were prepared and their structures solved by X-ray diffraction. The crystal structure of the parent ligand (4-BuO)C 6 H 4 COCH 2 COC 6 H 4 (4-OBu) 1 was also
The title compound (C 27 H 27 CuN 5 OS ) crystallizes in the orthorhombic space group Pbca with a = 11.1865(3)Å, b = 13.2006(3)Å, c = 34. 2304(1)Å, V = 5054.75(2)Å 3 , Z = 8, D cal = 1.401 Mg/m 3 at T = 293 K. The structure was solved by direct methods and refined by full-matrix least-squares proced