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Crystal structure of BaGd2NiO5 prepared by reaction of Ni metal with BaCO3 and Gd2O3

✍ Scribed by J. Amador; E. Gutiérrez Puebla; M.A. Monge; I. Rasines; J.A. Campa; J.M. Gomez de Salazar; C. Ruiz Valero

Book ID: 104201238
Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 142 KB
Volume: 32-33
Category: Article
ISSN: 0167-2738
DOI: 10.1016/0167-2738(89)90211-7

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For the first time ruby-red single crystals and powder samples of Na 5 [NiO 2 ][CO 3 ] were obtained via a redox reaction between nickel metal and CdO in the presence of Na 2 O and Na 2 CO 3 (molar ratios of CdO : Na 2 O : Na 2 CO 3 equal 1 : 3 : 2). The crystal structure has been refined from singl