𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Crystal structure of a vivianite-type mineral: Mg-rich erythrite, (Co2.16Ni0.24Mg0.60)(AsO4)2 · 8 H2O

✍ Scribed by Capitelli, Francesco; Elaatmani, Mohamed; Lalaoui, My Driss; Piniella, Juan F.

Book ID
119955683
Publisher
Oldenbourg Wissenschaftsverlag
Year
2007
Tongue
English
Weight
117 KB
Volume
222
Category
Article
ISSN
2194-4946

No coin nor oath required. For personal study only.

✦ Synopsis

The crystal structure of erythrite from Bouzaer, south Morocco, was refined through single crystal X-ray diffraction data, within monoclinic space group __C__2/m, with the following unit cell constants: a = 10.187(1) Å, b = 13.470(1) Å, c = 4.755(1) Å, β = 104.971(2)°, V = 630.3(2) Å^3^. Transition metal and magnesium cations are randomly distributed over two special positions Me(1) and Me(2), making up single and dimerical octahedral groups, connected by (AsO~4~) tetrahedra groups, in order to form infinite sheets down b. Such sheets are held together within the three-dimensional framework owing to the presence of an intricate hydrogen bond network. An infrared spectrum was collected in order to achieve information on the HOH bending modes of the erythrite.

📜 SIMILAR VOLUMES

Crystal Structures and Lattice Distortio
Crystal Structures and Lattice Distortions ofσ-Type Layered Vanadium Bronzes:σ-M0.25V2O5·H2O (M=Mg, Co, Ni)
✍ Yoshio Oka; Takeshi Yao; Naoichi Yamamoto 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 314 KB

New -type layered vanadium bronzes M 0.25 V 2 O 5 • H 2 O were hydrothermally synthesized for divalent metals of M ‫؍‬ Mg, Co, Ni in addition to the first-reported M ‫؍‬ Zn compound. The -type structures, consisting of V 2 O 5 layers with three octahedral and one tetrahedral V atoms and interlayer M

A Series of Borate-Rich Metalloborophosp
A Series of Borate-Rich Metalloborophosphates Na2 [MIIB3P2O11(OH)] ×0.67H2O (MII: Mg, Mn, Fe, Co, Ni, Cu, Zn): Synthesis, Structure and Magnetic Susceptibility.
✍ Tao Yang; Guobao Li; Jing Ju; Fuhui Liao; Ming Xiong; Jianhua Lin 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 10 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.