Crystal structure of 3-O-acetyl-1,2-O-isopropylidene-5-O-tosyl-α,D-gulofuranose-4,6-carbolactone
✍ Scribed by Phillips, S. E. V. ;Trotter, J.
- Book ID
- 114524061
- Publisher
- International Union of Crystallography
- Year
- 1977
- Weight
- 439 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0567-7408
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3-0-(6-0-Acetyl-2,3-anhydro-4-deoxy-a-L-ribo-hexopyranosyl)-l,2:5,6-di-O-isopropylidene-a-D-glucofuranose has been synthesised and its monocrystal investigated by X-ray diffraction methods. The compound crystallises in the orthorhombic system, space group P2,2,2t, with cell constants a = 8.790( 7),
The structures of the title compounds (2b and 3) have been investigated in the solid state by X-ray methods. The crystals of 2b are monoclinic, space group P2,, and of 3 orthorhombit, space grtup P2,2,2,. The cell dimensions are: for 2b, a = 9.910(2), b = 11;745W, c = 11.810(3) A, /3 = 97.32(l)"; a
Vicinal proton-proton spin-coupling constants for methyl 5-O-acetyl-2-O-benzoyl-3,4-O-isopropylidene-fl-L-idoseptanoside (1) have led to the assignment [1] of the twist-chair conformation, °'ITC2, 3 [2], for the seven-membered ring in 1 in which the pseudo-axis of symmetry passes through C-5. Since