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Crystal structure of 2,5,6-trimethyl-9-methoxy-4H-pyrrolo[3,2,1-ij ] quinolin-4-one

✍ Scribed by Alessandro Dolmella; Marino Nicolini

Publisher
Springer
Year
1990
Tongue
English
Weight
198 KB
Volume
20
Category
Article
ISSN
1572-8854

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Some photobiological properties of 2,6-dimethyl-9-methoxy-4H-pyrrolo[3,2,1-ij]quinolin-4-one (PQ) have been studied in comparison with 8-methoxypsoralen (8-MOP). In Ehrlich cells, PQ induced a moderate inhibition in DNA and RNA syntheses in the dark, which appeared to be more pronounced upon UVA irr

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## Abstract (__R__)‐5‐(diallylamino)‐5,6‐dihydro‐4__H__‐imidazo[4,5,1‐__ij__]quinolin‐2(1__H__)‐one (__12b__) was prepared in 9% overall yield from 3‐aminoquinoline. Reaction of __12b__ in ethyl acetate with tritium gas in presence of a 5% platinum on carbon catalyst afforded a mixture of (__R__)‐5