Crystal Structure of 2-Lithio-2-methyl-1,3-dithiane Tetramethylethylenediamine
✍ Scribed by Dipl.-Chem. René Amstutz; Prof. Dr. Dieter Seebach; Paul Seiler; Dr. Bernd Schweizer; Prof. Dr. Jack D. Dunitz
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 252 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0044-8249
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The crystal and molecular structures of a pair of diastereomeric 2-diphenylthiophosphinoylcis-(4,6-dimethyl)-1,3-dithianes 2 have been determined by the X-ray method. The differences in corresponding bond distances in cis-2 and trans-2 are discussed in context of the anomeric effect operating in thi