Crystal Structure and Magnetic Properties of the Dinuclear MnIICompound [Mn2(bpy)4(2-ClC6H4COO)2](ClO4)2·2EtOH
✍ Scribed by Verónica Gómez; Montserrat Corbella
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 305 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1572-8854
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## Abstract Four new dinuclear Mn^III^ complexes with the general formula [{Mn(bpy)L}(μ‐RCOO)~2~(μ‐O){Mn(bpy)L′}]^__n+__^ (bpy =2,2′‐bipyridine) have been synthesized with RCOO = 2‐MeC~6~H~4~COO (1, 2) and 2‐FC~6~H~4~COO (3, 4); the counteranion could be NO~3~^–^ (1, 3) or ClO~4~^–^ (2, 4), and a m
The copper(II) complex [Cu 2 (mal) 2 (H 2 O) 2 (4,4%-bpy)] (1) (H 2 mal=malonic acid and 4,4%-bpy= 4,4%-bipyridine) has been prepared and its structure determined by single crystal X-diffraction methods. Compound 1 has a two-dimensional square grid network structure. The square grids are stacked par