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Crystal structure and magnetic properties of [NMe4]4[Mn2(C3S5)4] (C3S2−5 = 4,5-dimercaptoc-1,3-dithiole-2-thionate)

✍ Scribed by Hatsue Tamura; Satoshi Tanaka; Gen-etsu Matsubayashi; Wasuke Mori


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
405 KB
Volume
232
Category
Article
ISSN
0020-1693

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Two new 1,2,3,5-dithiadiazoles, [4-(4Ј-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Ј-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t